Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1011 - 1014 (1992)
Update date:2022-08-11
Topics:
Furman, D. B.
Ivanov, A. O.
Belyankin, A. Yu.
Pogorelov, A. G.
Yanchevskaya, T. V.
Bragin, O. V.
The optimum conditions for the production of C9-C24 olefins with yields of 20-25percent (remainder hexenes) by oligomerization of liquid propylene at the Ni(PPh3)n (n = 2-4)-Et3Al2Cl3 catalytic system were determined by simplex design of experiments.It was shown that the obtained hexenes undergo secondary di- and trimerization reactions.Key words: oligomers, propylene, triphenylphosphinenickel, triethylaluminum.
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