Four Isomers of +. Distinguished by Collisional Activation

Article abstract of DOI:10.1002/oms.1210160709

Collisional activation of the molecular ions of 1-propanol, 2-propanol and methyl ethyl ether, and of the m/z 60 ion from 1,2-dimethoxyethane provides evidence for four distinct forms of ^+..Collision induced decompositions may be explained either by simple cleavages, by cyclic processes involving adjacent substituents, or by bicyclic processes of adjacent substituents.Evidence for a form of ^+. in which charge and radical site are separate is assembled from the spectra.