
Bulletin of the Chemical Society of Japan p. 561 - 569 (1997)
Update date:2022-08-17
Topics:
Young, Mark A.
DeBoer, Gary
Fujimoto, Akira
Iwasaki, Naoya
Traore, Hassime
Yourshaw, Ivan
The laser-induced fluorescence spectra and the fluorescence lifetimes of 1-methyl-2(1H)-pyridinimine and its deuterated analog were measured in a supersonic jet. The spectral results reveal a number of low frequency modes which are assigned to torsional motions involving the methyl group. The two major groups of peaks observed are ascribed to the presence of cis/trans conformers in the supersonic expansion.
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