Chelate Control in the Rhodium-catalysed Homogeneous Hydrogenation of Chiral Allylic and Homoallylic Alcohols

DOI: 10.1039/c39820000348

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Journal of the Chemical Society. Chemical communications p. 348 - 350 (1982)

Update date:2022-08-10

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Authors:

Brown, John M.

Naik, Ramachandra G.

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Article abstract of DOI:10.1039/c39820000348

Chelate bisphosphine rhodium complexes afford a high degree of stereoselection in the homogeneous hydrogenation of 3-phenylbut-3-en-2-ol and 4-phenylpent-4-en-2-ol, in opposite senses.

Full text of DOI:10.1039/c39820000348

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