TRANSITION METAL-PROMOTED REACTIONS. VII. NOVEL REACTIONS OF ACID CHLORIDES WITH PENTACARBONYLIRON IN AROMATIC SOLVENTS

DOI: 10.1016/S0022-328X(00)90019-6

Source and publish data:

Journal of Organometallic Chemistry p. 345 - 352 (1981)

Update date:2022-08-10

Topics:

Authors:

Luh, Tien-Yau

Lee, Kim Sze

Tam, S. W.

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Article abstract of DOI:10.1016/S0022-328X(00)90019-6

Upon treatment with Fe(CO)5 in an aromatic hydrocarbon solvent aromatic acid chlorides gave a mixture of triarylmethane and tetraarylethane.The reaction may proceed via benzaldehyde and diarylmethanol intermediates.A free radical mechanism is proposed.

Full text of DOI:10.1016/S0022-328X(00)90019-6

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