
Inorganic Chemistry p. 1871 - 1874 (1971)
Update date:2022-08-10
Topics:
Wynne, Kenneth J.
Pearson, Philip S.
The preparation of a series of 1:1 adducts of organoselenium and -tellurium trichlorides with antimony pentachloride is reported. These compounds are colorless or pale yellow moisture-sensitive crystalline solids. The adducts are soluble in CH2Cl2, insoluble in nonpolar organic solvents, and rapidly decomposed by donor organic media. The solid-state infrared spectra are interpreted in terms of the formulation [RMCl2+][SbCl6-], where M = Se, Te. Proton magnetic resonance data on these compounds are discussed.
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(2019)