Hydrolytic Metalloenzyme Models. Micellar Effects on the Activation of the Hydroxyl Groups of N-Alkyl-2-(hydroxymethyl)-imidazole Ligands by Cu2+ in the Transacylation of p-Nitrophenol Picolinate

Article abstract of DOI:10.1246/bcsj.64.74

The activation of the hydroxyl groups of two N-methyl/dodecyl-2-(hydroxymethyl)imidazole ligands by complexation with Cu²⁺ was investigated kinetically by observing the rates of the release of p-nitrophenol in the transacylation of p-nitropheny