Journal of the Chemical Society. Chemical communications p. 1031 - 1033 (1981)
Update date:2022-08-10
Topics:
Inoue, Yoshihisa
Ueoka, Toshihiko
Kuroda, Takayuki
Hakushi, Tadao
trans-Cycloheptene was prepared at -78 deg C by a singlet-sensitized photoisomerization of the cis-isomer, and its lifetime was measured at temperatures between -7.0 and +1.0 deg C to give thermodynamic parameters for the thermal trans-cis isomerization: Ea = 18.7 kcal mol-1, log A = 12.2.
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