
Phytochemistry p. 2761 - 2764 (1988)
Update date:2022-08-16
Topics:
Kinderlerer, Judith L.
Hatton, Paul V.
Chapman, Amanda J.
Rose, Malcolm E.
An essential oil (0.3percent v/w) was produced after fermentation of coconut for nine months by Chrysosporium xerophilum.Sixty per cent of the volatiles were aliphatic methyl ketones (C5-C13), esters and secondary alcohols whilst 38percent were present as free medium chain length fatty acids (C6-C12).A new class of ester, 2-heptyl esters of C8, C10 and C12 fatty acids, was identified by GC-MS and confirmed by synthesis.It is suggested that ester formation, ketone formation and alkane synthesis are mechanisms for removing medium chain fatty acids (C6-C12) which, if allowed to accumulate in the substrate, would be toxic to the fungus.Key Word Index - Cocos nucifera; Palmae; Chrysosporium xerophilum; fungus; substrate conversion coconut; methyl ketones; 2-heptyl esters; detoxification.
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