Recueil des Travaux Chimiques des Pays-Bas p. 362 - 365 (1988)
Update date:2022-08-29
Topics:
Floor, M.
Kieboom, A. P. G.
Bekkum, H. van
The use of γ-alumina and exchanged Y-zeolites as catalysts in the liquid-phase oxidation of cyclohexanol by tert-butyl hydroperoxide (tBHP) has been studied.With γ-alumina, cyclohexanone is formed, whereas the zeolites NaCeY and NaLaY give cyclohexyl formate as the main product.This compound is thought to originate from a zeolite-mediated rearrangement of tBHP to acetone and methanol, oxidation of methanol to formic acid and electrophilic addition of formic acid to cyclohexene (formed in situ from cyclohexanol).
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