Chemistry of Natural Compounds p. 24 - 27 (1991)
Update date:2022-08-18
Topics:
Koval'skaya, S. S.
Kozlov, N. G.
Shavyrin, S. V.
The individual E isomer of 4,6,6-trimethylbicyclo<3.1.1>heptan-2-one oxime has been obtained, and its transformations under the conditions of acid catalysis have been studied.The action of sulfuric acid on a solution of the oxime in acetonitrile leads to the selective formation of 5,7,7-trimethyl-2-azabicyclo<4.1.1>octan-3-one, while the action of hydrochloric acid with heating gives 4-isopropyl-3-methylaniline.
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