Phytochemistry p. 287 - 290 (1984)
Update date:2022-08-29
Topics:
Geigert, John
Neidleman, Saul L.
Witt, Susanne K. de
Dalietos, Demetrios J.
Bromoperoxidases do not directly oxidize the chloride ion; nevertheless, in the presence of bromide ions, chloride ions and hydrogen peroxide, bromoperoxidases react with alkenes and alkynes to produce bromochloro-derivatives.This same reaction is catalysed when seawater is the source of chloride and bromide ions.This suggests that bromonium ion-induced biosynthesis of chlorinated metabolites occurs in marine environments.The role of iodonium ions in the biosynthesis of chlorinated metabolites is also discussed.Key Word Index - Coralina sp.; Rhodophyta; biological halogenation; bromoperoxidase; enzymatic bromochlorination; marine chlorination; role of bromonium ions and iodonium ions; seawater.
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