Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3525 - 3534 (1986)
Update date:2022-08-16
Topics:
Hinman, A. Scott
Kydd, Ronald A.
Cooney, Ralph P.
The behaviour of cyanide on platinum electrodes at anodic potentials has been studied by voltammetric and Furier transform infrared reflectance spectroscopic techniques.The voltammetry shows that cyanide adsorbs on platinum at potential more negative than -0.8 V (SCE).Potential-sensitive infrared absorptions appearing between 2200 and 2250 cm-1 are tentatively assigned to strongly adsorbed cyanide species.Another band at 2074.5 cm-1 shows no change in wavenumber with potential and is thought to be associated with cyanide in the double-layer region.An absorption at 2169 cm-1, which appears with significant intensity at anodic potentials, has been attributed to bulk cyanate.Other features at 2093 and 2343 cm-1 are assigned to aqueous hydrogen cyanide and carbon dioxide, respectively, possibly formed as a result of changes in interfacial pH associated with electro-oxidation.
website:http://www.chinabarton.com
Contact:+86-573-82719618
Address:No. 162 Fumin Road, Honghe Town,
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】
website:http://www.chemboss.com.cn
Contact:+86-531-58591595
Address:No2.Hualong Road, Jinan, China
Jiaozuo Zhongwei Special Products Pharmaceutical Co.,Ltd.
website:http://www.zw-pvp.com
Contact:15302105619
Address:Jiaozuo,Henan,China (Mainland)
Nanjing Fubang Chemical Co.,Ltd
Contact:+86-25-83179199
Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
GUANGZHOU MEDCAN PHARMATECH LTD
website:http://www.gzmedcan.com
Contact:+86-20-82519649
Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
Doi:10.1080/00397911.2012.736006
(2013)Doi:10.1002/chem.201202141
(2012)Doi:10.1002/kin.550270403
(1995)Doi:10.1021/jm501181z
(2014)Doi:10.1134/S1070428013080046
(2013)Doi:10.1039/c5cy01493j
(2016)
