
Journal of Organic Chemistry p. 3545 - 3549 (1980)
Update date:2022-08-16
Topics:
House, Herbert O.
DeTar, Marvin B.
Sieloff, Ronald F.
VanDerveer, Don
Reaction of the bromo ketone 8 with Et3N resulted in the generation of solutions containing the strained enone 9.Enone 9 could be trapped with furan to form Diels-Alder adducts 10 and 11.However, enone 9 was consumed more rapidly in a reaction that formed the dimeric diketone 12.This dimeric product 12 is believed to be formed by an ene reaction (see structure 14) that occurs under mild conditions.
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