Journal of Organic Chemistry p. 2871 - 2875 (1984)
Update date:2022-08-04
Topics: Reduction Disproportionation Benzophenone Benzhydrol Hydrocarbon solvent
Choi, Chol-yoo
Stock, Leon M.
The reduction of benzophenone by hydrogen donor molecules such as tetralin and dihydroanthracene to give diphenylmethane was investigated in the temperature range 300-400 deg C.Several lines of evidence indicate that the reaction occurs in three distinct stages.The first stage is a radical process which gives benzhydrol.In the second stage, this intermediate undergoes an SN reaction to produce water and bis(diphenylmethyl) ether.The ether disproportionates in a readily initiated, free radical chain reaction to give diphenylmethane and benzophenone.
View MoreForsman Scientific(Beijing)co.,Ltd.
Contact:+86-10-64646565
Address:Rm No.1301, Building-2, No. A-13 Beiyuan Road, Chaoyang District Beijing, China, PR,
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD
Contact:86-21-60560171
Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
TAIXING BEST NEW MATERIALS CO., LTD
Contact:0523-87998158;
Address:No.18 Zhonggang Road,Taixing City ,Jiangsu , China
Shanghai ZaiQi Bio-Tech Co., Ltd.,
Contact:+86-21-5482 4098
Address:Bldg. No.7, No.201 MinYi Rd,Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Doi:10.1016/j.bmcl.2006.04.079
(2006)Doi:10.1016/j.tetlet.2004.01.048
(2004)Doi:10.1016/S0040-4039(01)82346-7
(1974)Doi:10.1007/BF00776986
()Doi:10.1007/BF00959743
(1991)Doi:10.1039/c3pp50385b
(2014)