Journal of the Chemical Society - Faraday Transactions p. 2331 - 2336 (1991)
Update date:2022-08-16
Topics:
Dobe, Sandor
Berces, Tibor
Szilagyi, Istvan
The kinetics of the reaction of CH3O with H have been studied under pseudo-first-order conditions with an excess of H using an isothermal discharge-flow reactor.Three different CH3O sources were used and the decay of a function of A second-order rate coefficient of (2.0 +/- 0.6) x 1013 cm3 mol-1 s-1 was determined for reaction CH3O + H -> products at room temperature and a slight positive temperature dependence was observed between 298 and 490 K.Formaldehyde formation was found to be the dominant reaction path (81 +/- 12percent).Further identified products were OH (7 +/- 3percent) and methanol (a few percent) which were produced by the decomposition and stabilization, respectively, of the initially formed bound adduct.
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