Journal of Molecular Spectroscopy p. 518 - 524 (1995)
Update date:2022-08-11
Topics:
Sakaizumi, Takeshi
Nishikawa, Motoi
Ohashi, Asamu
The microwave spectrum of trans-nitrosoethylene-15N (nitrosoethene) generated by pyrolysis of chloroacetaldehyde oxime-15N has been observed in the frequency range from 8.0 to 40.0 GHz.The rotational constants of the 15N species are determined to be A = 50390(201), B = 5057.00(3), and C = 4605.29(3) MHz.The rs-coordinates (a and b) of the nitrogen atom of trans-nitrosoethylene are determined to be 0.540(1) and 0.453 Anstroem, respectively.The three r0 structural parameters were fitted to four rotationalconstants (B and C) of the normal and 15N species.The bond length of r(C-N) and two bond angles of
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