Journal of the Chemical Society. Chemical communications p. 1794 - 1796 (1990)
Update date:2022-08-29
Topics:
Banfi, Stefano
Maiocchi, Alessandro
Moggi, Alberto
Montanari, Fernando
Quici, Silvio
Oxygenation of alkanes promoted by 30percent H2O2 and catalysed by chemically robust manganese(III)-tetraaryl porphyrins 2-4 is strongly accelerated by addition of small amounts of lipophilic carboxylic acids and lipophilic heterocyclic bases; cycloalkanes are converted into mixtures of alcohols and ketones at a rate of up to 125 turnovers min-1 in CH2Cl2-H2O solution at 0 deg C.
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