Hydrogen Peroxide Oxygenation of Alkanes catalysed by Manganese(III)-tetraarylporphyrins: the Remarkable Co-catalytic Effect of Lipophilic Carboxylic Acids and Heterocyclic Bases

DOI: 10.1039/c39900001794

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1794 - 1796 (1990)

Update date:2022-08-29

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Authors:

Banfi, Stefano

Maiocchi, Alessandro

Moggi, Alberto

Montanari, Fernando

Quici, Silvio

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Article abstract of DOI:10.1039/c39900001794

Oxygenation of alkanes promoted by 30percent H2O2 and catalysed by chemically robust manganese(III)-tetraaryl porphyrins 2-4 is strongly accelerated by addition of small amounts of lipophilic carboxylic acids and lipophilic heterocyclic bases; cycloalkanes are converted into mixtures of alcohols and ketones at a rate of up to 125 turnovers min^-1 in CH2Cl2-H2O solution at 0 deg C.

Full text of DOI:10.1039/c39900001794

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