Synthetic Communications p. 3193 - 3200 (1996)
Update date:2022-08-11
Topics:
Singh, Shiv P.
Kumar, Dalip
Kumar, Devinder
Reaction of 2-methylchromone (2) with phenylhydrazine provides 3-methyl-5-(o-hydroxyphenyl)-1-phenylpyrazole (6) as a major product. In contrast under similar conditions, heterocyclyhydrazines (8a-c) yield exclusively 5-ethyl-3-(o-hydroxyphenyl)-1-heterocyclylpyrazoles (9a-c). The structural assignments are based on an unambiguous synthesis and an analysis of NMR (1H and 13C) spectral data.
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