Kinetics and Mechanism of Halogen-Atom-Transfer Reactions between Haloalkanes and Several 17-Electron Transition-Metal Complex Negative Ions in the Gas Phase

DOI: 10.1021/ja00198a001

Source and publish data:

Journal of the American Chemical Society p. 5983 - 5992 (1989)

Update date:2022-08-28

Topics:

Authors:

Jones, Michael T.

McDonald, Richard N.

Schell, Philip L.

Ali, Mohammed H.

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Article abstract of DOI:10.1021/ja00198a001

The rate constants for the halogen-atom-transfer reactions between 11 17-electron transition-metal complex anion radicals (L(OC)_x-1M^.-) and up to 14 halogenated methanes and ethanes (RX) were measured in a flowing afterglow apparatus

Full text of DOI:10.1021/ja00198a001

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