Kinetics and Mechanism of Halogen-Atom-Transfer Reactions between Haloalkanes and Several 17-Electron Transition-Metal Complex Negative Ions in the Gas Phase

Article abstract of DOI:10.1021/ja00198a001

The rate constants for the halogen-atom-transfer reactions between 11 17-electron transition-metal complex anion radicals (L(OC)_x-1M^.-) and up to 14 halogenated methanes and ethanes (RX) were measured in a flowing afterglow apparatus