Chemistry of Heterocyclic Compounds p. 8 - 15 (1987)
Update date:2022-08-16
Topics:
Gavar, R. A.
Baumane, L. Kh.
Stradyn',Ya. P.
Fleischer, M. B.
Chernaeva, M.
Kovach, Ya.
The radical-anions of 2-carbonyl-containing derivatives of 5-nitrofuran were obtained by electrochemical generation.Their ESR spectra indicate the existence of a mixture of O,O-cis and O,O-trans rotational isomers.The parameters of the isomers were identified by INDO calculations.The more polar form (the cis isomer) is more stable in polar media.
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