Tetrahedron Letters p. 981 - 984 (1990)
Update date:2022-08-11
Topics:
Hawkins
Lewis
Raw
The anions of sulfonate esters derived from acidic alcohols olefinate carbonyl compounds. The dependence of the yield and stereochemistry of olefination on the sulfonate ester's alkoxy substituent are consistent with a mechanism were apicophilic alkoxy groups promote olefination via 10-S-5 intermediate 3.
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