FLASH VACUUM THERMOLYSIS OF 2-BROMOETHANOL. FORMATION OF &α-BROMOETHYLETHERS VIA 1-BROMOETHANOL.

DOI: 10.1016/S0040-4039(00)82381-3

Source and publish data:

Tetrahedron Letters p. 6489 - 6492 (1988)

Update date:2022-08-11

Topics:

Authors:

Jenneskens, Leonardus W.

Wiersum, Ulfert E.

Ripoll, Jean-Louis

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Article abstract of DOI:10.1016/S0040-4039(00)82381-3

Flash Vacuum Thermolysis of 2-bromoethanol (2) leads to the quantitative formation of 1-bromo-1-(1-bromoethoxy)ethane (5, di-α-bromoethylether).Low temperature IR spectroscopy shows that 5 arises from the dimerization of 1-bromoethanol (3), which is observed below -100 deg C as the primary product.

Full text of DOI:10.1016/S0040-4039(00)82381-3

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