Tetrahedron Asymmetry p. 3031 - 3034 (1997)
Update date:2022-08-17
Topics:
Martinez, Antonio Garcia
Vilar, Enrique Teso
Jimenez, Florencio Moreno
Bilbao, Carlota Martinez
New homochiral 1-norbornylthiotriflates 6 and 7 and 1-norbornanethiols 8 and 9 are easily prepared starting from naturally occurring 2-norbornanones 1. The key step is the reaction of chiral 2-norbornanethiones 2 with Tf2O under mild conditions.
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