Palladium-catalyzed arylation of allylic diols: Highly selective synthesis of phenyl-substituted allylic diols

DOI: 10.1016/0040-4039(95)01294-R

Source and publish data:

Tetrahedron Letters p. 6287 - 6290 (1995)

Update date:2022-08-17

Topics:

Authors:

Kang, Suk-Ku

Jung, Kyung-Yun

Park, Chan-Hee

Namkoong, Eun-Young

Kim, Tae-Hyun

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Article abstract of DOI:10.1016/0040-4039(95)01294-R

The coupling reaction of iodobenzene with allylic diols in the presence of Pd(OAc)₂ and nBu₃P as catalysts using K₂CO₃ as base afforded the phenyl-substituted allylic diols. However, under the same reaction conditions with Et₃N as base, phenyl-substituted α-hydroxy ketone was obtained.

Full text of DOI:10.1016/0040-4039(95)01294-R

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