The Decomposition of Trihalogenoacetic Acids in Dimethyl Sulphoxide: a Mild Route from Carbonyl Compounds to Trihalogenomethylethanols and Trihalogenomethyl Ketones

DOI: 10.1039/c39830000283

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 283 - 284 (1983)

Update date:2022-08-30

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Authors:

Atkins, Paul J.

Gold, Victor

Wassef, Wasfy N.

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Article abstract of DOI:10.1039/c39830000283

Solutions of trichloro- and tribromo-acetic acid in dimethyl sulphoxide in the presence of carbonyl compounds react at room temperature to give isolable products corresponding to the addition of H-CX3 across the carbonyl double bond.

Full text of DOI:10.1039/c39830000283

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