
Journal of the Chemical Society. Chemical communications p. 217 - 218 (1980)
Update date:2022-08-17
Topics:
Smith, Kevin M.
Langry, Kevin C.
Treatment with mercury(II) acetate of metal complexes of porphyrins bearing peripherally unsubstituted positions gives the corresponding mercurated derivatives; using the palladium-olefin reaction, this observation is exploited in the synthesis of coproporphyrin III tetramethyl ester (2), harderoporphyrin trimethyl ester (3), and isoharderoporphyrin trimethyl ester (4).
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