Deuterium magnetic resonance as a probe for organic reaction mechanisms: Epoxidation of 1(3)-tosylglycerol is a pure SN2 cyclisation

DOI: 10.1016/S0957-4166(00)82355-1

Source and publish data:

Tetrahedron Asymmetry p. 187 - 190 (1991)

Update date:2022-08-29

Topics:

Authors:

Rabiller

Mesbahi Mesbahi

Levayer Levayer

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Article abstract of DOI:10.1016/S0957-4166(00)82355-1

A stereoselective deuteriation of glycerol acetonide is used to prove by means of deuterium NMR spectroscopy that the cyclisation of glycerol tosylate into glycidol is a pure SN₂ mechanism.

Full text of DOI:10.1016/S0957-4166(00)82355-1

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