Journal of the Chemical Society. Perkin transactions II p. 329 - 331 (1991)
Update date:2022-08-28
Topics:
Kitani, Akira
Tsunetsugu, Shu-ichi
Sasaki, Kazuo
Non-enzymatic phosphorylation of ADP to ATP has been found to occur readily when Fe(III) ion is present in aqueous solutions of ADP and acetyl phosphate.As long as the reaction temperature is low enough (25 deg C or less), the phosphorylation of ADP to ATP proceeds to about 20percent conversion with 100percent selectivity.At higher temperatures, the yield decreases owing to the hydrolysis of acetyl phosphate.Among several phosphoryl donors studied, acetyl phosphate was found to be the best phosphorylating reagent.Creatine phosphate also produced ATP but the efficiency was very low.The phosphorylation of AMP was unsuccessful, even with acetyl phosphate.
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