Tetrahedron Letters p. 749 - 752 (1988)
Update date:2022-08-10
Topics:
Creary, Xavier
Mehrsheikh-Mohammadi, M. E.
The rate of the methylenecyclopropane rearrangement is greatly enhanced by the 4-pyridyl N-oxide group due to spin delocalization in the transition state which imparts nitroxide radical character to the biradical intermediate.
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Doi:10.1021/acs.orglett.5b00300
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