Journal of the Chemical Society. Perkin transactions I p. 498 - 502 (1981)
Update date:2022-08-16
Topics:
Nicotra, Francesco
Ronchetti, Fiamma
Russo, Giovanni
Lugaro, Giuseppe
Casellato, Marilena
<26-3H>Lanosterol (16) was administered to Pinus pinea and the <26-3H>isofucosteryl acetate (6) obtained was chemically transformed into <26-3H>cholesterol (13).Compound (13) was incubated with rat-liver mitochondria to yield the <3-3H>propionic acid.The data obtained are consistent with a biosynthetic pathway in which the pro-E isopropylidene methyl group of the Δ24-precursor becomes the pro-R isopropyl methyl group in isofucosterol.
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