Axial selectivity of 1,2-nucleophilic additions to 2-(Alkylidene) cyclohexanones: Is it higher than that of 2-cyclohexenones?

DOI: 10.1016/S0040-4039(00)73551-9

Source and publish data:

Tetrahedron Letters p. 2745 - 2748 (1993)

Update date:2022-08-17

Topics:

Authors:

You, Zhengqing

Koreeda, Masato

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Article abstract of DOI:10.1016/S0040-4039(00)73551-9

2-(Alkylidene)cyclohexanones embedded in steroid systems underwent 1,2-addition of both small and sterically demanding nucleophiles to yield exclusively the axial adducts, supporting the suggestion that 2-(alkylidene)cyclohexanones appear to have intrinsi

Full text of DOI:10.1016/S0040-4039(00)73551-9

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