Journal of the Chemical Society. Chemical communications p. 1677 - 1678 (1985)
Update date:2022-08-10
Topics:
Klusener, Peter A. A.
Hommes, Hendrik H.
Verkruijsse, Hermenn D.
Brandsma, Lambert
Treatment of isoprene with an excess of the couple potassium t-butoxide-lithium tetramethylpiperidine in tetrahydrofuran, followed by addition of a higher alkyl bromide or oxirane, gives the dienes H2C=CHC(=CH2)CH2R (R = alkyl or -CH2CH2OH) in reasonable yields.
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