Chemistry of Heterocyclic Compounds p. 176 - 179 (1999)
Update date:2022-08-25
Topics:
Sadchikova
Mokrushin
Pospelova
Selezneva
Reaction of 5-diazo-4-nitroimidazole with concentrated hydrochloric acid leads to 4-chloro-5-diazoimidazole. The same product is formed together with a small quantity of 5-chloro-4-nitroimidazole with 1 N hydrochloric acid, but with 0.1 N hydrochloric acid only chloronitroimidazole was isolated. The results obtained are explained with the aid of quantum chemical calculations. 1999 KluwerAcademic/Plenum.
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