Front Side Attack on the Bicyclopentane System by Halonium Ion; Halogenation of Dehydronoriceane

DOI: 10.1039/c39800000133

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 133 - 135 (1980)

Update date:2022-08-11

Topics:

Authors:

Katsushima, Takeo

Yamaguchi, Ryohei

Iemura, Satoshi

Kawanisi, Mituyosi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800000133

Halogenation of dehydronoriceane (1) in dichloromethane in the dark exclusively or predominantly gave the trans-4,5-dihalogenoethanonoradamantanes (2) providing decisive evidence for front side attack on the bicyclo<2.1.0>pentane system by halonium ions; the reaction is susceptible to the solvent and halogen used.

Full text of DOI:10.1039/c39800000133

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Octahydro-2,5-methano-1,6,7-metheno-1H-indene

Cas No:58008-63-2

R&D Labs maybe for 58008-63-2

Fujian Wanke Pharmaceutical Co., LTD.

Contact:+86-598-5026002

Address:Economic development zone,jiangle county
CHEM PLUS

Contact:0027-717-456976

Address:2ND FLOOR, 325 VAUSE ROAD, OVERPORT, 4001, SOUTH AFRICA
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone
QINGDAO NEW FLOURISH INTERNATIOANAL TRADE CO., LTD.

Contact:+86 532 80861829

Address:No. 1, Yinchuan East Road, 266061, Qingdao, China
Wuhan Benjamin Pharmaceutical Chemical Co.,Ltd

Contact:86-27-52341789

Address:Room 1518 B suite, optical valley time square, No 111 Guanshan Road, Hongshan District,Wuhan,Hubei Province,China.

Relevant to this article

Guanidinium-based derivatives: Searching for new kinase inhibitors

Doi:10.1016/j.ejmech.2014.05.025
(2014)
NiAl and CoAl materials derived from takovite-like LDHs and related structures as efficient chemoselective hydrogenation catalysts

Doi:10.1039/c3cy00611e
(2014)
Effect of La₂O₃-dopping on the Al₂O ₃ supported cobalt catalyst for Fischer-Tropsch synthesis

Doi:10.1016/j.molcata.2010.06.025
(2010)
Regioselectivity in Nucleophilic Ring Opening of 2-Methylaziridines. Lag of Bond Making as Model for the Abnormal Opening

Doi:10.1002/prac.19933350105
(1993)
Efficient one-step synthesis of C ₃-symmetrical benzenoid compounds mediated by SOCl ₂/EtOH

Doi:10.1080/00397911.2011.585731
(2012)
Doi:10.1021/ja01365a032
(1930)

Article Doi