Journal of the Chemical Society. Chemical communications p. 133 - 135 (1980)
Update date:2022-08-11
Topics:
Katsushima, Takeo
Yamaguchi, Ryohei
Iemura, Satoshi
Kawanisi, Mituyosi
Halogenation of dehydronoriceane (1) in dichloromethane in the dark exclusively or predominantly gave the trans-4,5-dihalogenoethanonoradamantanes (2) providing decisive evidence for front side attack on the bicyclo<2.1.0>pentane system by halonium ions; the reaction is susceptible to the solvent and halogen used.
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