Tetrahedron Letters p. 1887 - 1890 (1988)
Update date:2022-08-17
Topics:
Kitamura, Tsugio
Stang, Peter J.
Addition of NaN3 to RC<*>CIPh(1+)*OTs(1-) results in novel alkylidenecarbene-iodonium ylides, 5, R(N3)C=C=IPh, that by either protonation, ylide transfer or insertion of the derived carbene R(N3)C=C: give unique functionalized vinyl azides.
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