GENERATION, TRAPPING AND FATE OF ALKYLIDENECARBENE-IODONIUM YLIDES FROM THE ADDITION OF NaN3 TO ALKYNYLPHENYLIODONIUM TOSYLATES

DOI: 10.1016/S0040-4039(00)82069-9

Source and publish data:

Tetrahedron Letters p. 1887 - 1890 (1988)

Update date:2022-08-17

Topics:

Authors:

Kitamura, Tsugio

Stang, Peter J.

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Article abstract of DOI:10.1016/S0040-4039(00)82069-9

Addition of NaN3 to RC<*>CIPh(1+)*OTs(1-) results in novel alkylidenecarbene-iodonium ylides, 5, R(N3)C=C=IPh, that by either protonation, ylide transfer or insertion of the derived carbene R(N3)C=C: give unique functionalized vinyl azides.

Full text of DOI:10.1016/S0040-4039(00)82069-9

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