Chemical Communications p. 2257 - 2258 (1996)
Update date:2022-08-30
Topics:
Grellier, Mary
Pfeffer, Michel
N-Methyl-N-allyl-2-(1-acetoxyalIyl)benzylamine reacts in the presence of tetrakis(triphenylphosphine)palladium to afford a mixture of an isoindole, a 2-benzazepine and allyl acetate; the likely reaction pathway involves a multistep procedure whereby each Pd atom is implicated at least four times, the formation of the isoindole occuring first, followed by an isomerisation to the benzazepine derivative.
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