Tetrahedron Letters p. 2667 - 2670 (1985)
Update date:2022-08-25
Topics:
Jeffery, Tuyet
(E,E) and (E,Z) conjugated dienoates, dienones and dienals are obtained with high stereospecificity (<*>95percent) and in high yields from the corresponding (E) and (Z) vinylic halides and vinylic substrates (methyl acrylate, methyl vinyl ketone or acrolein), in the presence of potassium carbonate, tetrabutylammonium chloride and a catalytic amount of palladium acetate, in N,N-dimethylformamide at room temperature.
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