Hydroformylation of Vinyl Sulfones and Sulfoxides Catalyzed by a Zwitterionic Rhodium Complex. A Diastereoselective Process

DOI: 10.1021/jo00064a019

Source and publish data:

Journal of Organic Chemistry p. 3326 - 3329 (1993)

Update date:2022-08-18

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Authors:

Totland, Karen

Alper, Howard

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Article abstract of DOI:10.1021/jo00064a019

The hydroformylation of unsaturated sulfones and sulfoxides catalyzed by η⁶-C6H5B-Ph3Rh⁺ (1,5-COD) (1) was achieved in excellent yield and regiocontrol, with exclusive formation of branched-chain aldehydes.In the case of phenyl vinyl sulfoxide, evidence is presented for stereoselectivity in the reaction.

Full text of DOI:10.1021/jo00064a019

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