Journal of Organic Chemistry p. 3326 - 3329 (1993)
Update date:2022-08-18
Topics:
Totland, Karen
Alper, Howard
The hydroformylation of unsaturated sulfones and sulfoxides catalyzed by η6-C6H5B-Ph3Rh+ (1,5-COD) (1) was achieved in excellent yield and regiocontrol, with exclusive formation of branched-chain aldehydes.In the case of phenyl vinyl sulfoxide, evidence is presented for stereoselectivity in the reaction.
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