Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 39 - 54 (1983)
Update date:2022-08-17
Topics:
Alba, Francesca D'
Lorenzi, Sergio Di
This work attempts to provide a new theoretical model for oscillating chemical systems based on phase exchange and pulsating supersaturation.Phase exchange is of two types: one is steady exchange from the solution to the gas above it while the other is pulsating exchange between nucleations of bubbles of gas and the solution.The pulsating supersaturation allows nucleations of bubbles to form and oscillations to take place.We consider several variables, viz. temperature, bulk reaction, volume and size of the reactor, rate of stirring and pressure, and study their influence on the oscillations.The theoretical results are compared with some experimental results that can be explained by our new model.The system considered are the oxidation of malonic acid by bromate or iodate with cerium as catalyst and the oxidation of oxalic acid and formic acid.
View Morewebsite:http://www.hanwayschem.com
Contact:+86-18502787239(whatsapp)-
Address:18-1-802, Green Garden, Jianghan District, Wuhan 430023, China
Henan Yellow River New Material Technology Co.Ltd.
website:http://www.yellowriverchem.com
Contact:0086-373-7278760
Address:Chengguan Town, Yuanyang County
Shanghai ZaiQi Bio-Tech Co., Ltd.,
Contact:+86-21-5482 4098
Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
Xinjiang Zhongtai Chemical Co., Ltd.
Contact:+86-991-8788172
Address:NO.78 XISHAN RD.URUMQI，CHINA
Wuhan Konberd Biotech Co., Ltd.
Contact:+86-27-87205925
Address:NO.666, Gaoxin Road, Eastlake High-tech zone
Doi:10.1002/chem.201002236
(2011)Doi:10.1039/d0ra00879f
(2020)Doi:10.1007/BF02900610
(1931)Doi:10.1016/j.dyepig.2016.08.010
(2017)Doi:10.1021/ja00512a043
(1979)Doi:10.1016/0304-4165(68)90132-3
(1968)
