Easy access to both enantiomers of C7-C12 segment of epothilones

Article abstract of DOI:10.1080/00397919908086597

Both enantiomers of the C7-C12 segment (5 and 6) of epothilones A and B (1 and 2) were effectively synthesized starting from the methyl (R)- and (S)- hydroxy-2-methylpropionates (3 and 4) using the Grignard cross-coupling reaction mediated by cuprous (I)

Full text of DOI:10.1080/00397919908086597

Synthetic Communications
ISSN: 0039-7911 (Print) 1532-2432 (Online) Journal homepage: http://www.tandfonline.com/loi/lsyc20
Easy Access to Both Enantiomers of C7-C12
Segment of Epothilones
Shinji Tanimori , Koichi Tanimoto & Mitsunori Kirihata
To cite this article: Shinji Tanimori , Koichi Tanimoto & Mitsunori Kirihata (1999) Easy Access
to Both Enantiomers of C7-C12 Segment of Epothilones, Synthetic Communications, 29:24,
4353-4360, DOI: 10.1080/00397919908086597
To link to this article: http://dx.doi.org/10.1080/00397919908086597
Published online: 25 Sep 2007.
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Date: 07 April 2016, At: 10:49