Unexpected Outcome of NbCl5-Promoted Sakurai Reaction: Mechanistic Implications Relevant to C4H7+ Species

DOI: 10.1016/0040-4039(94)02332-6

Source and publish data:

Tetrahedron Letters p. 899 - 902 (1995)

Update date:2022-08-11

Topics:

Authors:

Maeta, Hideki

Nagasawa, Tetsuya

Handa, Yasuhiko

Takei, Toru

Osamura, Yoshihiro

Suzuki, Keisuke

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Article abstract of DOI:10.1016/0040-4039(94)02332-6

Use of NbCl5 in the Sakurai reaction gave an unexpected outcome.Allylsilane reacted with aldehyde in 2:1-stoichiometry with concomitant formation of a cyclopropane ring.Mechanistic implications of this anomalous reaction related to C4H7⁺ specie

Full text of DOI:10.1016/0040-4039(94)02332-6

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