Synthesis of Bicyclic Cyclopentanols by Photoreductive Cyclization of δ,ε-Unsaturated Ketones

DOI: 10.1021/jo00372a018

Source and publish data:

Journal of Organic Chemistry p. 4196 - 4200 (1986)

Update date:2022-08-11

Topics:

Authors:

Belotti, D.

Cossy, J.

Pete, J. P.

Portella, C.

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Article abstract of DOI:10.1021/jo00372a018

Bicyclic cyclopentanols were synthesized by intramolecular radical addition from photochemically induced electron transfer to δ,ε-unsaturated ketones.The donor was HMPA (neat) or Et3N (in CH3CN).Irradiation of δ,ε-ethylenic ketones and β-keto esters in HM

Full text of DOI:10.1021/jo00372a018

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