Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1249 - 1253 (1990)
Update date:2022-08-16
Topics:
Rudchenko, V. F.
Ignatov, S. M.
Chervin, I. I.
Aliev, A. E.
Kostyanovskii, R. G.
The electrophilically catalyzed splitting of the N-O bond of dimethoxyamine results in the formation of methoxynitrenium ion, which in reaction with nucleophiles exhibits properties of an ambidentate cation - it methylates rigid nucleophiles and epiminates olefins.The stereospecificity of the addition of the nitrenium ion to cis-2-butene indicates its existence in a singlet electronic ground state.
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(1956)
