Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1249 - 1253 (1990)
Update date:2022-08-16
Topics:
Rudchenko, V. F.
Ignatov, S. M.
Chervin, I. I.
Aliev, A. E.
Kostyanovskii, R. G.
The electrophilically catalyzed splitting of the N-O bond of dimethoxyamine results in the formation of methoxynitrenium ion, which in reaction with nucleophiles exhibits properties of an ambidentate cation - it methylates rigid nucleophiles and epiminates olefins.The stereospecificity of the addition of the nitrenium ion to cis-2-butene indicates its existence in a singlet electronic ground state.
View More
Zhushan County Tianxin Pharmaceutical & Chemical Co., Ltd.
Contact:0086-719-4224892
Address:Tutang Road, Chengguan Town, Zhushan County, Hubei Province
Arshine Pharmaceutical Co., Limited
website:http://www.cnarshine.com
Contact:0731-88503671
Address:Room 1109.Block C3, Lugu Enterprise Plaza,No.27 Wenxuan Road,Changsha National Hi-Tech Industrial Development Zone,Hunan ,P.R.China
Shenyang Xingzhenghe Chemical Co., Ltd.
Contact:024-23509232
Address:No. 33, Naner Road, Heping Dist.
Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd
Contact:+86-0372-3662335 +86-0372-3661988
Address:hanling industrial park anyang
Contact:+86-532-80762375
Address:No. 6, Hongkong Middle Road, Qingdao, China
Doi:10.1021/ic901523u
(2009)Doi:10.1246/cl.1999.149
(1999)Doi:10.1002/aoc.2935
(2013)Doi:10.3390/molecules24061030
(2019)Doi:10.1039/b811234g
(2008)Doi:10.1139/v56-074
(1956)
