Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1249 - 1253 (1990)
Update date:2022-08-16
Topics:
Rudchenko, V. F.
Ignatov, S. M.
Chervin, I. I.
Aliev, A. E.
Kostyanovskii, R. G.
The electrophilically catalyzed splitting of the N-O bond of dimethoxyamine results in the formation of methoxynitrenium ion, which in reaction with nucleophiles exhibits properties of an ambidentate cation - it methylates rigid nucleophiles and epiminates olefins.The stereospecificity of the addition of the nitrenium ion to cis-2-butene indicates its existence in a singlet electronic ground state.
View More
Shanghai Kangxin Chemical Co., Ltd
Contact:+86 21 60717227
Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
Shijiazhuang Yunxuan Im&Export Co.,Ltd.
Contact:+86-311-83037514
Address:No.6 Hongbin Road
Contact:+86-0760-85282375
Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Feiyang Biotechnology Co., Ltd.
Contact:+86-533-7866339
Address:Qilu Chemistry Park, 200m north of Management Community Building of Park
website:http://www.josunpharma.com
Contact:+86-311-80715268 80766839
Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China
Doi:10.1021/ic901523u
(2009)Doi:10.1246/cl.1999.149
(1999)Doi:10.1002/aoc.2935
(2013)Doi:10.3390/molecules24061030
(2019)Doi:10.1039/b811234g
(2008)Doi:10.1139/v56-074
(1956)
