
Russian Chemical Bulletin p. 1495 - 1497 (1993)
Update date:2022-08-10
Topics:
Budyka, M. F.
Kantor, M. M.
Thermolysis of azobenzene in a melt and in solution results in the formation of aniline.The possible directions of the reaction are considered.Comparison of the enthalpies of the reaction proves that the cleavage of a ?-bond in the N=N group to form a biradical intermediate is thermodynamically more favorable than that of a C-N ?-bond.
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