Journal of the Chemical Society. Chemical communications p. 2659 - 2660 (1994)
Update date:2022-08-11
Topics:
Papadogianakis, Georgios
Maat, Leendert
Sheldon, Roger A.
The renewable basic chemical 5-hydroxymethylfurfural (HMF) is selectively carbonylated to the new compound 5-formylfuran-2-acetic acid using a water-soluble palladium complex of trisulfonated triphenylphosphine as the catalyst in an acidic aqueous medium at 70 deg C and 5 bar CO pressure; when hydrogen iodide is the acid component, the reaction follows a different course and HMF is selectively reduced to 5-methylfurfural.
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