Regioselective nucleophilic ring opening of oxabicyclic compounds

DOI: 10.1016/0040-4039(93)89008-E

Source and publish data:

Tetrahedron Letters p. 773 - 776 (1993)

Update date:2022-08-17

Topics:

Authors:

Lautens, Mark

Chiu, Pauline

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Article abstract of DOI:10.1016/0040-4039(93)89008-E

The ring opening of unsymmetrical oxabicyclic compounds was found to be highly regioselective, giving rise to products from the attack of the nucleophile distal to the bridgehead substituent. Ozonolysis furnished acyclic chains with up to five stereocenters and differentiated ends.

Full text of DOI:10.1016/0040-4039(93)89008-E

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