Tetrahedron Letters p. 1279 - 1282 (1984)
Update date:2022-08-17
Topics:
Felkin, Hugh
Fillebeen-Khan, Tauqir
Gault, Yvonne
Holmes-Smith, Rupert
Zakrzewski, Janusz
Homogeneous catalytic dehydrogenation of cyclooctane into cyclooctene has been effected by means of a variety of iridium and ruthenium polyhydrides, at 150 deg C, in the presence of an olefin as the hydrogen acceptor; best results (45-70 catalytic turnovers) have been achieved with (iPr3P)2IrH5, <(p-F-C6H4)3P>2IrH5 and <(p-F-C6H4)3P>3RuH4.
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