Samarium(II) iodide mediated intermolecular coupling reactions of N,N-dibenzyl-α-haloamides with carbonyl compounds

DOI: 10.1055/s-1996-4324

Source and publish data:

Synthesis p. 970 - 974 (1996)

Update date:2022-08-16

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Authors:

Aoyagi, Yutaka

Asakura, Rie

Kondoh, Nobuko

Yamamoto, Rieko

Kuromatsu, Takeshi

Shimura, Ai

Ohta, Akihiro

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Article abstract of DOI:10.1055/s-1996-4324

Samarium(II) iodide mediated coupling reactions of α-haloamides with carbonyl compounds are found to give N,N-dibenzyl-β-hydroxyamides (4a-i, 5a-i, and 6a) in good yields under mild reaction conditions. The transformation of 4a and 5a to N,N-dibenzyl-3-phenylpropanamide (7) and β-hydroxycarboxylic acid (8), respectively, are described.

Full text of DOI:10.1055/s-1996-4324

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