Tetrahedron Letters p. 1899 - 1902 (1999)
Update date:2022-08-11
Topics:
Creton
Rezaei
Marek
Normant
Carbozincation of a metallated propargylic ether can lead to a gem bismetallic reagent with a good 1,3-diastereoselection. This latter can be relayed to a 1,4-diastereoselection, when the gembismetallic thus formed is monohalogenated to give a carbenoid which rearranges at room temperature.
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(1994)
